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New PDF release: Elem. Metallurgy & Heat-Treating (Making Knives)

By B. Gaston

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Extra resources for Elem. Metallurgy & Heat-Treating (Making Knives)

Example text

Corrosion Electrochemistry Some metals such as silver are univalent, while other metals such as iron, titanium, and uranium are multivalent and possess positive charges as high as 6 (see Fig. 8). 10) is general and applies to all corrosion reactions. 3 Faraday’s Law If the current generated by one of the anodic reactions expressed earlier was known, it would be possible to convert this current to an equivalent mass loss or corrosion penetration rate with a very useful relation discovered by Michael Faraday, a nineteenth century pioneer in electrochemistry.

2. Paparazzo E. Surfaces—lost and found. Nature Materials 2003; 2: 351–3. 3. Cushman AS, Gardner HA. The Corrosion and Preservation of Iron and Steel. New York: McGraw-Hill, 1910. 4. LaQue FL. What can management expect from a corrosion engineer? Materials Performance 1985; 25: 82–4. 5. Uhlig HH. The cost of corrosion in the United States. Chemical and Engineering News 1949; 27: 2764. 6. Koch GH, Brongers MPH, Thompson NG, Virmani YP, Payer JH. Corrosion Costs and Preventive Strategies in the United States.

In both cases the valences of the elements on the left of each reaction remain what it is on the right. The valences of iron, zinc, hydrogen, and oxygen elements remain unchanged throughout the course of these reactions, and it is consequently not possible to divide these reactions into individual oxidation and reduction reactions. Reference 1. Mapes RS, Berkey WW. X-ray diffraction methods for the analysis of corrosion products. In: Ailor WH, ed. Handbook on Corrosion Testing and Evaluation. New York: John Wiley & Sons, 1971; 697–730.

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Elem. Metallurgy & Heat-Treating (Making Knives) by B. Gaston


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